Nonequilibrium steady states in a vibrated-rod monolayer : tetratic, nematic, and smectic correlations
نویسندگان
چکیده
We study experimentally the nonequilibrium phase behaviour of a horizontal monolayer of macroscopic rods. The motion of the rods in two dimensions is driven by vibrations in the vertical direction. Aside from the control variables of packing fraction and aspect ratio that are typically explored in molecular liquid crystalline systems, due to the macroscopic size of the particles we are also able to investigate the effect of the precise shape of the particle on the steady states of this driven system. We find that the shape plays an important role in determining the nature of the orientational ordering at high packing fraction. Cylindrical particles show substantial tetratic correlations over a range of aspect ratios where spherocylinders have previously been shown [1] to undergo transitions between isotropic and nematic phases. Particles that are thinner at the ends (rolling pins or bails) show nematic ordering over the same range of aspect ratios, with a well-established nematic phase at large aspect ratio and a defect-ridden nematic state with large-scale swirling motion at small aspect ratios. Finally, long-grain, basmati rice, whose geometry is intermediate between the two shapes above, shows phases with strong indications of smectic order. PACS numbers: 61.30.Eb,45.70.-n Nonequilibrium steady states in a vibrated-rod monolayer 2
منابع مشابه
Biaxial nematic and smectic phases of parallel particles with different cross sections.
We have calculated the phase diagrams of one-component fluids made of five types of biaxial particles differing in their cross sections. The orientation of the principal particle axis is fixed in space, while the second axis is allowed to freely rotate. We have constructed a free-energy density functional based on fundamental-measure theory to study the relative stability of nematic and smectic...
متن کاملCompositional and orientational ordering in rod - coil diblock
The phase behavior of a melt of monodisperse rod-coil diblocks is studied. We derive a Landau free energy functional for both a compositional and a nematic order parameter. The excluded volume interaction between the rod blocks is modeled by an attractive Maier-Saupe interaction. The incompatibility between rodand coil blocks is modeled by the usual Flory-Huggins interaction. For a large volume...
متن کاملNanostructures of liquid crystal phases in mixtures of bent-core and rod-shaped molecules.
We report small angle x-ray scattering (SAXS) studies of isotropic, nematic, and smectic mesophases formed by binary mixtures of bent-core (BC) and rod-shaped (RS) molecules. While optical studies indicate that the components are fully miscible, SAXS reveals fascinating structures that are consistent with segregation on a nanoscopic scale. We find that tilted smectic clusters, which have been p...
متن کاملCompositional and orientational ordering in rod - coil diblock copolymer melts
The phase behavior of a melt of monodisperse rod-coil diblocks is studied. We derive a Landau free energy functional for both a compositional and a nematic order parameter. The excluded volume interaction between the rod blocks is modeled by an attractive Maier-Saupe interaction. The incompatibility between rodand coil blocks is modeled by the usual Flory-Huggins interaction. For large volume f...
متن کاملSelf-assembly of 2D membranes from mixtures of hard rods and depleting polymers().
We combine simulations and experiments to elucidate the molecular forces leading to the assembly of two dimensional membrane-like structures composed of a one rod-length thick monolayer of aligned rods from an immiscible suspension of hard rods and depleting polymers. Computer simulations predict that monolayer membranes are thermodynamically stable above a critical rod aspect ratio and below a...
متن کامل